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If you're having a problem with a user or something else on IRC, you can query a channel operator, or "chanop".
You can find out more about chanops here as well as requesting these rights here.
If you cannot get on the IRC channel in the first place, you may ask for assistance on the talk page.
In some IRC clients you will only see the "@" for all admin and mods.In other clients, "@" denotes an Op (Operator), "&" denotes a Super Op, and "~" is the channel's founder. If they are breaking the rules in the chat room, /msg an admin or mod (someone with an "@", "&" or "~" in front of their name).